pOH is the mirror image of pH — it measures hydroxide ion [OH-] concentration instead of hydrogen ion concentration.
pOH is the mirror image of pH — it measures hydroxide ion [OH-] concentration instead of hydrogen ion concentration. Since pH and pOH always add up to 14 in water at room temperature, knowing one instantly tells you the other.
A solution has [OH-] = 1×10⁻³ mol/L. pOH = −log₁₀(1×10⁻³) = 3, so pH = 14 − 3 = 11 — a basic solution.
A measure of hydroxide ion concentration in a solution, calculated as pOH = −log10[OH⁻].
At 25°C, pH + pOH = 14, so knowing one lets you calculate the other directly.
pOH is sometimes more convenient when working directly with basic (alkaline) solution calculations.